A pretty obscure question, and old movie

I don’t remember much, but it was an Old movie, something with husband and wife and he is suspect of something I think near end she is angry with her husband, something to do with crime. He is behind glass and she spits angrily but the saliva is on the window.
I think.ahe overheard him confessing something or something similar, I was very young, probably at least 20 years ago in my estimate.
And for some reason I remember the actress as Salma Hayek, but it is not her as far as I can tell, maybe someone who looks similar.

Thank you in advance

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