Movie opening scene is a man dropping an impassive woman from the roof of a highrise. She lands on the roof of a car.
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I solved it myself:
Tall, Dark and Deadly (1995)
A successful female architect, just recovering from a broken relationship, comes under the spell of a charming stranger, unaware that he is a psychopath who is driven to possess any woman with whom he falls in love – and to kill her if she does not totally return that love.
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I don’t know if it starts off this way but there is a couple woman falling/pushed from a tall apartment building in Looker 1981